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http://www.amset.info/outlook/pst-password.aspI did it once on a 3 meg PST, on outlook 2k.. so best wishes on 2k3 if they use the Unicode format or larger than 2gb pst files.

http://support.microsoft.com/kb/q287497/

Creating A Personal Folder in Microsoft OutlookSince email server storage is extremely expensive, it’s useful to be able to retain old, low value emails without having to manually save them out to the hard drive as individual files. Instead, you can save old e...